Trisha Yearwood is the very first celebrity guest on 'The Chris Isaak Hour,' a new show making its debut Thursday on the Bio channel. On the inaugural episode, Yearwood and Isaak sing her hit, 'Wrong Side of Memphis.' Watch their duet below, followed by a collaboration on Isaak's song, 'Breaking Apart,' after the jump.

Trisha Yearwood & Chris Isaak - 'Wrong Side of Memphis' (Live)

Trisha Yearwood & Chris Isaak - 'Breaking Apart' (Live)
'The Chris Isaak Hour' airs Thursdays on the Bio channel at 10 PM ET.