Keith Urban, Vince Gill and Hunter Hayes have been added to the list of performers for the 46th Annual CMA Awards. Additionally, the first-round of presenters include Martina McBride, Kellie Pickler, Sugarland and the Band Perry.

Vince, who hosted the ceremony for a record 12 times, will be performing with Kelly Clarkson. The pair trade vocals on the tune "Don't Rush," which will be included on the Female Vocalist of the Year nominee's upcoming album, Greatest Hits -- Chapter 1.

Brad Paisley and Carrie Underwood are hosting the show for the fifth consecutive time. Winners will be announced during the live telecast on Thursday, Nov. 1 beginning at 8:00 PM ET on ABC.

Watch a Report on This Year's CMA Awards Nominees

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Taylor Swift, Blake Sheldon, Miranda Lambert Top CMA Nomineestry{document.getElementById("fivemin-widget-blogsmith-image-667545").style.display="none";}catch(e){}